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Formulas/physics/Current Electricity/Resistivity from Microscopic Parameters

Resistivity from Microscopic Parameters

Resistivity in terms of electron mass m, carrier density n, charge e, and mean relaxation time τ. Directly derivable from the drift velocity expression and Ohm's law.
Class 12
Derivation

Derivation

From the drift velocity: vd=eEτ/mv_d = eE\tau/m.

Current density: J=nevd=ne2τmEJ = nev_d = \dfrac{ne^2\tau}{m}E

From Ohm's law in microscopic form J=σEJ = \sigma E:

σ=ne2τm\sigma = \frac{ne^2\tau}{m}

Since ρ=1/σ\rho = 1/\sigma:

ρ=mne2τ\boxed{\rho = \frac{m}{ne^2\tau}}

Physical interpretation of each factor

FactorRoleEffect on ρ
mmheavier electrons accelerate lessρ ↑
nnmore carriersρ ↓
eestronger force and more chargeρ ↓
τ\taufewer collisions, longer free pathρ ↓

Temperature dependence recovered

For metals, nn is nearly constant. As TT rises, more intense lattice vibrations reduce τ\tau, so ρ1/τ\rho \propto 1/\tau increases — consistent with the empirical formula RT=R0(1+αT)R_T = R_0(1 + \alpha T).

Note
This derivation assumes the Drude (free electron) model. It gives the correct functional form but predicts $\tau$ values that are sometimes off by an order of magnitude. Quantum mechanics (Fermi-Dirac statistics) gives a more accurate picture.